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1.1K views · 17 reactions | Researchers from the MIT report a borane analogue of diazoalkane compounds in Science (https://ccdc-info.com/4fYhBUn). The diazoborane functional group is stabilized by an NHC, and is shown to be reactive in [3+2] cycloadditions with alkynes. The compound also acts as a borylene source with the loss of N2.  CSD Entry TOSFEQ: https://ccdc-info.com/3XcJ2Ch #FeaturedStructureFriday #Crystallography | Cambridge Crystallographic Data Centre (CCDC) | Facebook
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